Easiest thing to do is use the Report button, plain and simple. If you come across anything at all, be it a mod, an image, a forum thread, or anything else, that you think is, or might be, against the rules, then just use the Report button. One of the Admin team will then be able to deal with it. It's as simple as that.
Having been an Admin and moderator on other sites I know full well that it's generally a thankless job that requires quite a bit of work. More so when it's unpaid and you're simply doing it because you want to. The Admin team here on the Nexus forums and mod sites is, quite frankly, incredibly small for the amount of user traffic the sites generate and despite that, I believe they do an incredible job of keeping things running. For those who have never checked, there are 3 Admins + 3 Moderators, that's just 6 people looking after the whole Nexus family of sites! As such they will depend quite heavily on members using the Report button to notify them of any possible content that may break the rules in any way.
If anyone believes that any rule-breaking content has slipped under the net it's more than likely because no-one has bothered to report that content. Don't sit back and think that someone else will report it, just click the Report button and let the Admin team know about it. I suspect the Admin team would say they'd prefer to receive multiple reports about one piece of content than receive no reports at all. If you help the Admin team do their job then you're helping them to make the Nexus family of sites better for everyone.