Having the same issue:
Error: libloadorder failed to create a game handle. Details: Failed to parse ini file, error at line 48, column 38: unknown character in \xHH form: Libloadorder error
at l.handleResponse (C:\Program Files\Black Tree Gaming Ltd\Vortex\resources\app.asar.unpacked\bundledPlugins\gamebryo-plugin-management\index.js:2:619583)
at C:\Program Files\Black Tree Gaming Ltd\Vortex\resources\app.asar.unpacked\bundledPlugins\gamebryo-plugin-management\index.js:2:618056
at Array.forEach (<anonymous>)
at Socket.<anonymous> (C:\Program Files\Black Tree Gaming Ltd\Vortex\resources\app.asar.unpacked\bundledPlugins\gamebryo-plugin-management\index.js:2:618039)
at Socket.emit (node:events:513:28)
at addChunk (node:internal/streams/readable:324:12)
at readableAddChunk (node:internal/streams/readable:297:9)
at Readable.push (node:internal/streams/readable:234:10)
at Pipe.onStreamRead (node:internal/stream_base_commons:190:23)